详细资料
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中文名：汤杰
原名：汤迪乃
职业：演员
参演电影：《描金凤》《红运高照》《貂蝉》《武则天》等
人物经历
1996年回国工作。
研究方向
有机合成与有机合成方法学、金属有机化学、甾体药物化学。
主要贡献
汤杰他主持国家自然科学基金、上海市科委重点研究项目有多项。
主要论文及专利：
1.Anefficientsilica-graftedpoly-(L)-leucinecatalystforasymmetricepoxidationofa,b-unsaturatedketone,J.Mol.Catal.A:Chemical,2007
2.Palladium-CatalyzedRingEnlargementofAryl-SubstitutedMethylene-cyclopropanestoCyclobutenes,J.Am.Chem.Soc.,2006,128,7430-7431.
3.Palladium-CatalyzedCross-CouplingReactionof2-Iodo-4-(phenylchalcogenyl)-1-butenes,J.Org.Chem.,2005,70,10420-10425.
4.Enynylationof2-Iodo-4-(phenylchalcogenyl)-1-butenesviaIntramolecularChelation:ApprochtotheSynthesisofConjugatedDienynesorTrienynes,Org.Lett.,2005,7(14),3085.
5.Palladium-benzimidaliumsaltcatalystsystemsforSuzukicoupling:developmentofapracticalandhighlyactivepalladiumcatalystsystemforcouplingofaromatichalideswitharylboronicacids,Tetrahedron,2005,61,9783-9790.
6.Asymmetricepoxidationofa,b-unsaturatedketonescatalyzedbysilica-graftedpoly-(L)-leucinecatalysts,TetrahydronLett.,2005,46,5665.
7.ANovelandEfficientProcessforPreparationof2,4-Diphenyl-4-methyl-1-penteneinBrönstedAcidicIonicLiquid[Hmim]+BF4-,Chin.J.Chem.,2005,23,581.
8.SuzukiCouplingReactionCatalyzedbyCyclopalladatedComplexesofTertiaryArylaminesinIonicLiquid,Chin.Chem.Lett.,2005,16(9),1173.
9.Oxidationoftoluenestobenzoicacidsbyoxygeninnon-acidicsolvents,Tetrahedron,2004,60,1225.
10.Anunprecedentedrhodium-catalysedself-conjugatereduction,cross-couplingtandemreactionofcinnamaldehydeswitharylboronicacids,Chem.Commun.,2004,1192-1193.
11.AnefficientprocedureforprotectionofcarbonylsinBronstedacidicionicliquid[Hmim]BF4,TetrahedronLett.,2004,45(25),4963.
12.ImmobilizationofHX:[Hmim]XasHalogenatingAgent,RecyclableCatalystandMediumforConversionofAlcoholstoAlkylHalides,Chin.J.Chem.,2004,22,619.
13.HomocouplingofArylIodidesCatalyzedbyCyclopalladatedComplexesofTertiaryArylamines,Chin.J.Chem.,2004,22(5),419.
14.BronstedAcidicIonicLiquid1-MethylimidazoliumTetrafluoroborate:AGreenCatalystandRecyclableMediumforEsterification,GreenChemistry,2003,5,38.
15.Rhodium-catalyzedHeck-typereactionofarylboronicacidswitha,b-unsaturatedesters:tuningb-hydrogeneliminationvs.hydrolysisofalkylrhodiumspecies,Chem.Commun.,2003,2438.
16.Cross-couplingofarylboronicacidswithterminalalkynesinair,TetrahedronLett.,2003,44,8709–8711.
17.Developinganionicmediumforligandless-palladium-catalysedSuzukiandHeckcouplings,J.Mol.CatalysisA:Chemical,2003,206,193-198.
18.Synthesis,BiochemicalPropertiesandMolecularModellingStudiesofOrganometallicSpecificEstrogenReceptorModulators(SERMs),theFerrocifensandHydroxyferrocifens:EvidenceforanAntiproliferativeEffectofHydroxyferrocifensonbothHormone-DependentandHormone-IndependentBreastCancerCellLines,Chem.Eur.J.2003,9,5223-5236.
19.Heptadecafluorooctanesulfonicacidcatalyzedreactionsofmethylenecyclopropanesonaromaticamines,sulfonamidesandalcoholsinsupercriticalcarbondioxide,GreenChem.,2003,5,85-88.
20.CrystalStructureofChiralAcetato-bridgedBinuclearCyclopalladatedComplex[Pd(μ-O2CMe)(S-C6H4CHMeNH2)]2,Chin.J.Chem.,2003,21(8),1039.
21.Heckreactionofiodoareneswithmethylacrylatecatalyzedbycyclopalladatedcomplexesoftertaryarylaminesimmobilizedinionicliquid[Bmim]+BF4-,Chin.J.Chem.,2003,21,1111.
22.Synthesisofcyanobenzaldehydes(o-,m-,p-)bymolecularoxygenoxidationmethods,Chin.J.Chem.,2002,20,76.
23.CyclopalladatedcomplexesoftertiaryarylaminescatalyzingtheHeckreactioninionicliquid[Bmim]+BF4,J.Organomet.Chem.,2002,651,146.
24.ImmobilizationofPd(II)catalystsforcyclopropanationofionicliquid,Chin.J.Chem.,2002,20,114.
25.Anovelring-openingreactionofmethylenecyclopropaneswitharomaticaminescatalyzedbyLewisacids,TetrahedronLetters,2002,43,8019-8024.
26.ANewConvenientMethodfortheSynthesisofFormylFerrocene,Syn.Commun.,2000,1657.
获奖记录
1999年获“上海市育才”奖和华东师范大学“奥力孚”奖；2002年获“宝钢优秀教师”奖，同年被评为“教育部优秀骨干教师”；2004年获“上海市优秀教育工作者”、华东师范大学“师德标兵”称号；2005年获华东师范大学“优秀德育工作者”称号。